Thermal-induced self-healing bio-based vitrimers: Shape memory, recyclability, degradation, and intrinsic flame retardancy

编号 020035803

推送时间 20220829

研究领域 林产化工 

年份 2022 

类型 期刊 

语种 英语

标题 Thermal-induced self-healing bio-based vitrimers: Shape memory, recyclability, degradation, and intrinsic flame retardancy

来源期刊 Polymer Degradation and Stability

期 第358期

发表时间 20220801

关键词 Epoxy vitrimers;  Self-healing;  Recycling;  Degradable;  Flame retardancy; 

摘要 The structure of epoxy resin determines its flammable property, non-reprocessing, unrecyclable, and nonde-gradable, which limits their application. Thus, a novel disulfide bond-containing dynamic covalent thiol-ene crosslinked epoxy vitrimers (TECEVs) as covalently adaptable networks were synthesized. Also, the structure-property relationship of polymeric compounds was investigated. The insoluble vitrimers networks demonstrated faster stress relaxation with 107 s at 200 degrees C, and obtained lower activation energy between 70.52 and 110.57 k.Jmol(-1). In addition, the dynamic nature of the disulfide bond allowed the damaged TECEVs to be thermal-induced self-repairing and self-healing materials with efficiencies 100% at 160 degrees C. It was discovered that TECEVs can be reprocessed at 160 degrees C with the recovery of mechanical strength above 80% and be completely decomposed in an ethanol-acid catalyst solution. Moreover, typical TECEVs can function with excellent flame retardancy and illustrated a high limit oxygen index (LOI, 27.45-28.36%), and UL-94 V-0 rating was achieved. This work could provide an efficient strategy for the synthesis of "biobased self-repairing flame retardant" networks and contribute to the development of high-performance sustainable polymers.

服务人员 尚玮姣

服务院士 宋湛谦

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