Preparation of Rosin Pentaerythritol Ester Over an Fe3O4-Supported ZnO Catalyst

编号 020024402

推送时间 20200622

研究领域 林产化工 

年份 2020 

类型 期刊 

语种 英语

标题 Preparation of Rosin Pentaerythritol Ester Over an Fe3O4-Supported ZnO Catalyst

来源期刊 Catalysis Letters

期 第244期

发表时间 20200512

关键词 Rosin;  Fe3O4@SiO2–ZnO;  Rosin pentaerythritol ester;  Esterification;  Stability; 

摘要 Conversion of rosin to its pentaerythritol ester provides a means of improving its water resistance, alkali resistance, and oxidation resistance, thereby increasing its stability. Rosin pentaerythritol ester is much more amenable to industrial applications than the parent compound. To overcome the difficulty of catalyst recovery and its associated high cost during the synthesis of rosin pentaerythritol ester, Fe3O4-supported ZnO catalysts, such as Fe3O4@ZnO and Fe3O4@SiO2–ZnO, have been designed and synthesized. The structures, morphologies, and compositions of the materials have been characterized by TEM, XRD, and XPS. The results of esterification reactions demonstrate that Fe3O4@SiO2–ZnO has excellent catalytic performance and stability. The degree of esterification in the production of rosin pentaerythritol ester reached 87.9%, far exceeding the yields attained with other catalysts. Moreover, the catalyst could be reused five times without incurring a loss of activity. The effects of zinc source, zinc loading, and reaction conditions on the esterification have been investigated in detail. This study provides a class of heterogeneous catalysts with excellent properties for the synthesis of rosin pentaerythritol ester.

服务人员 尚玮姣

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