编号
020034502
推送时间
20220530
研究领域
林产化工
年份
2022
类型
期刊
语种
英语
标题
Facile strategy for preparing rhodamine B/ZrO2 composite fluorescent film with combined advantages of high emission intensity and outstanding water-resistance
来源期刊 Materials Research Bulletin
期
第345期
发表时间
20220601
关键词
ZrO 2 films;
Rhodamine B;
Fluorescence;
Water-resistance;
Rosin;
摘要
The RB/ZF composite film prepared by immobilizing rhodamine B (RB) on ZrO2 film (ZF) exhibits strong fluorescence intensity but poor water-resistance. In this paper, rosin, octadecane-1, 18-dicarboxylic acid (OA) and silane coupling agent were used as hydrophobic modifiers to investigate the method to improve water resistance of RB/ZF and maintain its strong fluorescence intensity as well. The influencing factors including modifier dosage, molecular structure, RB concentration and alkyl chain length of coupling agent on fluorescence performance and water-resistance of composite film were studied in detail and the related reasons were discussed. Results demonstrate that the film modified by the combination of rosin, OA and coupling agent has both favorable fluorescence performance and excellent water-resistance. The emission intensity of the optimized film is 94.5% of that of RB/ZF. Meanwhile, after immersion in various aqueous environments, there is no obvious difference in emission spectrum or intensity.
服务人员
尚玮姣
服务院士
宋湛谦
PDF文件
浏览全文