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Improved mechanical properties of flexible bio-based polymeric materials derived from epoxy mono/di-abietic acid and soyabean oil



编号 020020905

推送时间 20191021

研究领域 林产化工 

年份 2019 

类型 期刊 

语种 英语

标题 Improved mechanical properties of flexible bio-based polymeric materials derived from epoxy mono/di-abietic acid and soyabean oil

来源期刊 INDUSTRIAL CROPS AND PRODUCTS

第209期

发表时间 20190531

关键词 Abietic acid;  Soyabean oil;  Bio-based;  Epoxy;  Coating; 

摘要 The study aims at synthesizing a novel, flexible bio-based coating material with enhanced mechanical properties. The isomers of abietic acid, typically sourced from pines were epoxidized using glycidol via carbodiimide chemistry. A mono and di-epoxy based abietic acid were successfully synthesized and as characterized by IR, Mass, and NMR spectroscopy. The content of the epoxy-based abietic acid was varied before mixing with epoxidized soyabean oil. The resultant admix was cured to a transparent biomaterial. It exhibits superior characteristics that can be fine-tuned by altering the proportion of epoxidized abietic acid relative to the triglyceride. It was found that the biomaterial prepared by slight addition of abietic acid dimer (0.75%) performed better than mono abietic acid (1%) in terms of thermal and mechanical properties.

服务人员 尚玮姣

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