编号
020034801
推送时间
20220620
研究领域
林产化工
年份
2022
类型
期刊
语种
英语
标题
Fast and sustainable recycling of epoxy and composites using mixed solvents
来源期刊 Polymer Degradation and Stability
期
第348期
发表时间
20220501
关键词
Epoxy;
Chemical Recycling;
Transesterification;
Carbon Fiber Reinforced Composite;
Reduced Pressure Distillation;
摘要
Chemical recycling of thermosets and composites can reclaim polymer matrix and high-value reinforcement to protect the environment and save resources. However, efficient and sustainable chemical recycling of epoxy thermosets is still a significant challenge, specifically, improving the decomposition rate, easily separating and reusing the decomposed components under mild condition. Herein, we report the fast and sustainable recycling of epoxy and composites by small-molecule assisted bond exchange reaction (BER) in a mixed solvent. The anhydride-cured epoxy resin with embedded catalyst was rapidly decomposed by the mixed solvent containing a high boiling point alcohol and inert good solvent via transesterification below 150°C at normal pressure. The epoxy decomposition rate was optimized by altering the good solvent types and solvents mixing ratios. We found the epoxy decomposition rate was the fastest in dimethylformamide/ethylene glycol (50/50) due to balanced solvent diffusion/swelling and reaction rate. After epoxy decomposition, the depolymerized epoxy oligomer (DEO) and residual solvents were readily separated by reduced pressure distillation below 80°C. The DEO as an additive (up to 20%) was repolymerizated with fresh epoxy resin to make epoxy materials, which showed similar mechanical properties to the original epoxy with slight deterioration even for several recycling cycles. The reclaimed solvent was used for the next round of recycling. With the optimized condition, carbon fiber reinforced epoxy composite was also recycled to reclaim the high-value carbon fiber with unchanged mechanical properties. This work presents a sustainable and fast recycling paradigm for industrial-grade epoxy and composite with potential for upscale engineering applications.
服务人员
尚玮姣
服务院士
宋湛谦
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