Crude Wood Rosin and Its Derivatives as Hydrophobic Surface Treatment Additives for Paper and Packaging

编号 020027402

推送时间 20210118

研究领域 林产化工 

年份 2021 

类型 期刊 

语种 英语

标题 Crude Wood Rosin and Its Derivatives as Hydrophobic Surface Treatment Additives for Paper and Packaging

来源期刊 ACS OMEGA

期 第274期

发表时间 20201215

关键词 Maleic-Anhydride;  Water-vapor;  Starch;  Coatings;  Resins;  Pulp;  Acid; 

摘要 The aim of this work is to obtain better water resistance properties with additives to starch at the size press. A further goal is to replace petroleum-based additives with environmentally friendly hydrophobic agents obtained by derivatization of wood rosin. A crude wood rosin (CWR) sample was methylated and analyzed with gas chromatography-mass spectrometry (GC-MS). Methyl abietate, dehydroabietic acid, and abietic acid were the main constituents of the sample. The crude wood rosin samples were fortified with fumaric acid and then esterified with pentaerythritol. Fortified and esterified wood rosin samples were dissolved in ethanol and emulsified with cationic starch to make them suitable as hydrophobic additives for surface treatment formulations in mixtures with starch. These hydrophobic agents (2% on a dry weight basis in a cationic starch solution) were applied to paperboard, bleached kraft paper, and test liner paper using a rod coater with a target pickup of 3-5 gsm. The solution pickup was controlled by varying the rod number. The amounts of hydrophobic material applied in the preparation of the paper samples were 32.2, 48.6, and 35.1 lb/ton pickup compared to three types of base papers. Basic surface features of fortified and fortified and esterified rosin-treated paper were compared with base paper and paper treated with starch alone. Lower Cobb(60) values were obtained for fortified and esterified samples than for linerboard samples that had been surface-sized just by starch. Thus, as novel hydrophobic additive agents, derivatives of CWR can be a green way to increase hydrophobicity while reducing starch consumption in papermaking.

服务人员 尚玮姣

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