Fully recyclable carbon fiber reinforced vanillin-based epoxy vitrimers

编号 020033004

推送时间 20220214

研究领域 林产化工 

年份 2022 

类型 期刊 

语种 英语

标题 Fully recyclable carbon fiber reinforced vanillin-based epoxy vitrimers

来源期刊 European Polymer Journal

期 第330期

发表时间 20211204

关键词 Lignin based monomer;  Vanillin;  Epoxy vitrimer;  Carbon fiber recycling;  Thermosetting resin; 

摘要 Fabrication of recyclable and reprocessable epoxy vitrimers is opening more application opportunities for carbon fiber (CF) recycling. Despite the extensive study of epoxy thermosets from lignin-based monomer of vanillin, however, few works have been focused on its vitrimers, let alone their mechanical, interfacial, solvent resistance and fully recyclable properties of vanillin-based epoxy vitrimers /CF composite. Here the effect of four types of curing agents on the above properties has been carefully studied. Two-layer CF reinforced vanillin-based epoxy vitrimers composites that was cured with Isophoronediamine shows higher tensile strength at break and Young’s Modulus than those of Bisphenyl A epoxy (E51)/CF and other epoxy vitrimers/CF composites, which reaches 571?MPa and 11.7 GPa, respectively. All vanillin-based epoxy vitrimers are easily degradable at room temperature in acid solution except for that cured with 4,4′-Diaminodiphenylmethane. The surface morphology and chemical structure of CF are not altered after degradation. Importantly, completely recyclable vanillin-based epoxy vitrimers are achieved by imine exchange reaction; however, the mechanical and thermal properties of it are slightly inferior to the origins. This work demonstrates that the mildly degradable, fully recyclable vanillin-based epoxy vitrimers and readily recycling of CF are desirable for the development of lignin based functional materials.

服务人员 尚玮姣

服务院士 宋湛谦

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