Thermo-mechanical behavior of elastomers with dynamic covalent bonds

编号 020023402

推送时间 20200413

研究领域 林产化工 

年份 2020 

类型 期刊 

语种 英语

标题 Thermo-mechanical behavior of elastomers with dynamic covalent bonds

来源期刊 International Journal of Engineering Science

期 第234期

发表时间 20191216

关键词 Elastomer;  Dynamic covalent bond;  Nanocomposite;  Thermo-mechanical response;  Constitutive modeling; 

摘要 Natural and synthetic rubbers (networks of polymer chains connected by irreversible chemical cross-links) cannot be repaired after damage, while discarded rubbers cannot be economically recycled and reprocessed. To avoid this shortcoming, a number of elastomers with dynamic covalent bonds have recently been synthesized that demonstrate recyclability, malleability and capability of autonomous self-healing due to thermally triggered bond-exchange reactions.A constitutive model is developed for the thermo-viscoelastic and thermo-viscoplastic responses of elastomers whose chains are bridged by adaptive bonds with the associative mechanism of rearrangement. Material parameters in the governing equations are determined by fitting observations in tensile tests, cyclic tests, relaxation tests and creep tests in a wide range of temperatures on covalently cross-linked rubber, thermoplastic elastomer, several elastomers and elastomer nanocomposites with dynamic covalent bonds, and epoxy vitrimers. Characteristic features are discussed of the thermo-mechanical behavior of elastomers with dynamic bonds and structure–property relations are established for these materials.

服务人员 尚玮姣

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