Synthesis and solution properties of hydrophobically associating water-soluble copolymer with dynamic covalent bond

编号 020035504

推送时间 20220808

研究领域 林产化工 

年份 2022 

类型 期刊 

语种 英语

标题 Synthesis and solution properties of hydrophobically associating water-soluble copolymer with dynamic covalent bond

来源期刊 Colloids and Surfaces A: Physicochemical and Engineering Aspects

期 第355期

发表时间 20220525

关键词 Water soluble copolymer;  Hydrophobic association;  Dynamic covalent bond;  Surface and interfacial activity;  Salt resistance and shear tolerance; 

摘要 The hydrophobically associating water-soluble terpolymer was synthesized by free-radical copolymerization of acrylamide (AM), diacetone acrylamide (DAAM), and cetyl dimethylallyl ammonium chloride (ACD), and then was crosslinked by acyl hydrazone bonds. The viscosity properties, surface activity, interfacial activity, and the emulsifying ability of the copolymer solution were characterized by the rotational viscometer, tensiometer, interface rheometer, optical microscope, and Formulaction Turbiscan Expert Lab optical analyzer. The dynamism, salt resistance, shear tolerance, and temperature resistance were investigated by viscosity analysis and rheometer measurements. The results showed that the copolymer solution combined chemical with physical cross-linking had high viscosity maintained at high salinity and shear rate. This understanding of the contribution of dynamic covalent bonds and hydrophobic association to the viscosity properties should be informative for the design of oil agents.

服务人员 尚玮姣

服务院士 宋湛谦

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