编号
020036602
推送时间
20221024
研究领域
林产化工
年份
2022
类型
期刊
语种
英语
标题
Rosin acid and SiO2 modified cotton fabric to prepare fluorine-free durable superhydrophobic coating for oil-water separation
来源期刊 Journal of Hazardous Materials
期
第366期
发表时间
20221015
关键词
Rosin acid;
Cotton fabric;
Superhydrophobic coating;
Oil -water separation;
Fluorine -free;
摘要
Currently, fluorides and long-chain aliphatic compounds are the most frequent low surface energy chemicals utilized in the preparation of superhydrophobic coatings, but associated environmental risks and instability restrict their potential application in oil-water separation. This research described a superhydrophobic coating based on rosin acid and SiO2 modified cotton fabric to overcome this challenge. By means of spray impregnation and UV-assisted click reaction, sulfhydryl modified rosin acid (RA), Octavinyl-POSS, and SiO2 were grafted onto the surface of cotton fabric to obtain RA-SiO(2 )superhydrophobic coating with rough surfaces such as lotus leaf and low surface energy. The RA-SiO2 superhydrophobic coating had favorable self-cleaning ability, and also adsorbed various light and heavy oils to achieve efficient separation of oil-water mixtures. The separation efficiency was 96.3% and the permeate flux was 6110.84 (L.m(-2).h(-1)) after 10 repetitions. The RA-SiO2 super -hydrophobic coating was found to be effective in separating oil-in-water and oil-in-water emulsions, and the separation mechanism was elaborated. In addition, it could effectively separate emulsions even after mechanical abrasion and chemical immersion, and had excellent stability. The fluorine-free and environmentally friendly low-cost superhydrophobic coating based on rosin acid is expected to play a significant potential in oil-water separation applications due to its excellent separation performance.
服务人员
尚玮姣
服务院士
宋湛谦
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