Preparation of eco-friendly natural rosin-based SiO2-NH2@GO hybrid sealant and study on corrosion resistance of Fe-based amorphous coating for steel substrate

编号 020037702

推送时间 20230109

研究领域 林产化工 

年份 2022 

类型 期刊 

语种 英语

标题 Preparation of eco-friendly natural rosin-based SiO2-NH2@GO hybrid sealant and study on corrosion resistance of Fe-based amorphous coating for steel substrate

来源期刊 Carbon

期 第377期

发表时间 20230105

关键词 Sealant;  Graphene oxide;  Nature rosin;  Corrosion resistance;  Fe-based amorphous coating;  Silica; 

摘要 Sealing treatment is an effective method to prolong the service life of Fe-based amorphous coatings for steel substrates. Common sealants always have the disadvantages of releasing amounts of volatile organic compounds (VOC) and are expensive, prompting researchers to develop an eco-friendly, low cost and high-performance sealant. However, their simultaneous improvement is restricted by some inevitable contradictions among them. Herein, natural rosin was introduced as a sealing material and an eco-friendly natural rosin-based SiO2-NH2@GO hybrid sealant was successfully prepared by the sol-gel method. In addition, the functional nanocomposite SiO2-NH2@GO was added to the hybrid sealant system to achieve the purpose of extending the service life of the sealant. The filling efficiency, adhesion, thermal stability and long-term corrosion resistance of hybrid sealants were investigated. The study showed that the adhesion of the hybrid sealant to the Fe-based amorphous coating was improved by 10.59% after adding the nanocomposite. The hybrid sealant reaches maximum thermal decomposition at 414.3 C. The corrosion current density (i(corr)) of the sample NSG-0.5%o still decreased by about two orders of magnitude after immersion for 672 h (0#, i(corr) = 1.39 x 10-4 A/cm(2); NSG-0.5%o, i(corr) = 1.51 x 10(-6) A/cm(2)). Full immersion experiments explore the failure process of hybrid sealants, where corrosion always tends to propagate with unmelted particles. The hybrid sealant prepared has the ad-vantages of being eco-friendly and low cost, and provides a specific preparation process, which provides a new direction for the development of the sealant.

服务人员 尚玮姣

服务院士 宋湛谦

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