编号
020031802
推送时间
20211122
研究领域
林产化工
年份
2021
类型
期刊
语种
英语
标题
High-strength and self-healable poly (acrylic acid) /chitosan hydrogel with organic-inorganic hydrogen bonding networks
来源期刊 Polymer
期
第318期
发表时间
20210707
关键词
Self-healing hydrogel;
Hydrogen bonding;
Organic-inorganic;
摘要
Bentonite?is a natural clay mineral with high cationic exchange properties and plays an important role in organic-inorganic composite hydrogels. We report an organic-inorganic cross-linked self-healing hydrogel with excellent mechanical properties by introducing acrylic acid-modified bentonite (AABT) into its cross-link network. AABT with unsaturated double bonds was co-polymerized with AA to construct the hybrid cross-link network of the hydrogel. Then, the carboxyl groups in the PAA chain reacted with CS to form a physically cross-linked network with a?hydrogen bond?structure. As confirmed by FTIR, XRD, XPS and SEM, the AABT participated in the formation of the hydrogel network, and the hydrogen bonds between PAA and CS chains were formed. Our AABT-PAA/CS hydrogels possessed?tensile strength, compressive modulus and elongation at break as high as 0.96?MPa, 4.5?MPa and 1331%, respectively. Besides, our hydrogels also exhibited excellent self-healing properties, with recovered rate stress and strain of ~76.6% and ~77.7% after 4?h, respectively.
服务人员
尚玮姣
服务院士
宋湛谦
PDF文件
浏览全文