Synthesis and Characterization of Allyl Terpene Maleate Monomer

编号 020027502

推送时间 20210125

研究领域 林产化工 

年份 2021 

类型 期刊 

语种 英语

标题 Synthesis and Characterization of Allyl Terpene Maleate Monomer

来源期刊 SCIENTIFIC REPORTS

期 第275期

发表时间 20191216

关键词 polyesters;  terpenes;  allyl terpene maleate monomer; 

摘要 Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower reaction temperatures. Using terpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, terpene-diallyl maleate adduct, was prepared by D-A addition, hydrolysis, and substitution reaction. The resultant monomer was characterized for the first time. The synthesized product will be a versatile monomer and a very important intermediate, having broad application prospects. The synthesized monomer will replace similar aromatic compounds in certain applications because of its low-toxicity and sustainability. The synthesized monomer with two terminal olefin structures has great free radical polymerization potential, according to its physical and chemical properties and exploratory experimentation.

服务人员 尚玮姣

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