Metal Coordination in Polyimine Covalent Adaptable Networks for Tunable Material Properties and Enhanced Creep Resistance

编号 020038405

推送时间 20230227

研究领域 林产化工 

年份 2022 

类型 期刊 

语种 英语

标题 Metal Coordination in Polyimine Covalent Adaptable Networks for Tunable Material Properties and Enhanced Creep Resistance

来源期刊 MACROMOLECULAR RAPID COMMUNICATIONS

期 第384期

发表时间 20230101

关键词 covalent adaptable networks;  dynamic covalent chemistry;  imines;  metal coordinations;  polymers; 

摘要 Covalent adaptable networks (CANs) can replace classical thermosets, as their unique dynamic covalent bonds enable recyclable crosslinked polymers. Their creep susceptibility, however, hampers their application. Herein, an efficient strategy to enhance creep resistance of CANs via metal coordination to dynamic covalentimines is demonstrated. Crucially, the coordination bonds not only form additional crosslinks, but also affect the imine exchange. This dual effect results in enhanced glass transition temperature (T-g), elasticmodulus (G ') and creep resistance. The robustness of metal coordination is demonstrated by varying metal ion, counter anion, and coordinating imine ligand. All variations in metal or anion significantly enhance the material properties. The T-g and G ' of the CANs are correlated to the coordination bond strength, offering a tunable handle by which choice of metal can steer material properties. Additionally, large differences in T-g and G ' are observed for materials with different anions, which are mostly linked to the anion size. This serves as a reminder that for coordination chemistry in the bulk, not onlythe metal ion is to be considered, but also the accompanying anion. Finally, the reinforcing effect of metal coordination is proved insensitive to the metal-ligand ratio, emphasizing the robustness of the applied method.

服务人员 尚玮姣

服务院士 宋湛谦

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