pH-Responsive Wormlike Micelles Formed by an Anionic Surfactant Derived from Rosin

编号 020027505

推送时间 20210125

研究领域 林产化工 

年份 2021 

类型 期刊 

语种 英语

标题 pH-Responsive Wormlike Micelles Formed by an Anionic Surfactant Derived from Rosin

来源期刊 JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY

期 第275期

发表时间 20200916

关键词 rosin;  surfactant;  pH-responsive;  wormlike micelles;  viscoelastic solution; 

摘要 A novel pH-responsive wormlike micellar viscoelastic solution was constructed by a rosin-based anionic surfactant (Na-MPA-AZO-Na) in the presence of cetyltrimethylammonium bromide (CTAB). The viscoelasticity, aggregate morphology, and pH-responsiveness of the pH-responsive wormlike micelles have been investigated through the method of rheology and cryogenic-transmission electron microscopy. Its corresponding mechanism has been studied using H-1 NMR and H-1-H-1 2D NOESY HNMR. The zero-shear viscosity (eta(0)) of the wormlike micellar solution rapidly decreases by 3 orders of magnitude as the pH increases from 5.21 to 9.56. The viscoelastic fluids and water-like solutions can be converted by tuning the pH between 3.62 and 12.00, and the corresponding aggregates also transform between wormlike micelles and spherical micelles. In addition, the wormlike micellar cross-sectional diameter is approximately 10 nm, which is remarkably larger than that of the common wormlike micelles. The phenomenon can be attributed to the large steric volume of the rosin rigid skeleton. When the pH is 12.00, a "pseudo" Gemini surfactant is constructed by Na-MPA-AZO-Na and CTAB through the electrostatic interactions. Wormlike micelles also can be formed with the increasing concentrations. The eta(0) of the wormlike micellar system shows strong dependence on concentration with an exponent of 9.6 (eta(0) proportional to C-9.6). This work further promotes new applications of forest resources.

服务人员 尚玮姣

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