Valorization of Waste: Sustainable Organocatalysts from Renewable Resources

编号 020027704

推送时间 20210208

研究领域 林产化工 

年份 2021 

类型 期刊 

语种 英语

标题 Valorization of Waste: Sustainable Organocatalysts from Renewable Resources

来源期刊 CHEMSUSCHEM

期 第277期

发表时间 20200207

关键词 biomass;  biopolymers;  green chemistry;  organocatalysis;  renewable resources; 

摘要 One of the greatest challenges facing our society is to reconcile our need to develop efficient and sophisticated chemical processes with the limited resources of our planet and its restricted ability to adsorb pollution. Organocatalysis has allowed many issues to be addressed in the development of sophisticated, but less polluting, processes. However, minimizing waste also means an efficient utilization of raw and renewable materials. Waste biomass represents an alternative to conventional petroleum-based chemical manufacturing and is a highly attractive renewable resource for the production of chemicals and high-value-added organocatalysts. Recent achievements in the use of renewable biomass feedstocks for the synthesis of organocatalysts are presented. Their application in synthetic methodologies, including multicomponent reactions, which are performed under solvent-free conditions or in eco-friendly reaction media, as well as recycling and reusing the organocatalysts, is illustrated. A few pioneering examples that demonstrate the potential of these promoters in asymmetric synthesis have also been documented. In particular, this review covers examples on the use of hetero- and homogeneous organocatalysts derived from 1) waste biopolymers, such as chitosan, alginic acid, and cellulose; ii) renewable platform molecules, such as levoglucosenone, isosorbide, mannose, d-glucosamine, and lecithin; 3) terpenes and rosin, such as pinane, isosteviol, and abietic acid; and iv) natural proteins (gelatin, bovine tendons, silk fibroin proteins).

服务人员 尚玮姣

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