编号
020033705
推送时间
20220404
研究领域
林产化工
年份
2021
类型
期刊
语种
英语
标题
Photochemical Aging of Eco-Friendly Wood Coatings Derived from Vegetable Oils
来源期刊 ACS Applied Polymer Materials?
期
第337期
发表时间
20211123
关键词
wood;
epoxy coatings;
modified vegetable oils;
UV degradation;
color modifications;
structural modifications;
摘要
Eco-friendly polymer coatings for wood surface protection against ultraviolet (UV) radiation were synthesized from grapeseed, soybean, and linseed epoxidized oils and diglycidyl ether of bisphenol A cross-linked with a resin acid/maleic anhydride adduct. Pine wood was coated with the synthesized formulations through immersion followed by a thermal curing protocol, resulting in semi-transparent film-covered surfaces. The wood and coated wood samples were exposed to 500 h of UV irradiation (lambda = 365 nm) during which color changes were correlated with structural modifications, through Fourier transform infrared spectroscopy. Color changes indicated an improved resistance to UV radiation of the coated samples compared to pristine wood. Reflectance spectra measurements were also undertaken. Gloss retention increased and mass loss decreased for the coated wood samples during UV irradiation compared to non-coated wood. The coatings were tested in terms of water absorption, adhesion, and hardness. The coated wood surfaces showed reduced water absorption, good adhesion, and increased hardness during UV irradiation. All presented data recommend the eco-friendly films as future candidates for wood surface protective coatings against the destructive action of environmental factors.
服务人员
尚玮姣
服务院士
宋湛谦
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