编号
020031703
推送时间
20211115
研究领域
林产化工
年份
2021
类型
期刊
语种
英语
标题
Bio-based vitrimer-like polyurethane based on dynamic imine bond with high-strength, reprocessability, rapid-degradability and antibacterial ability
来源期刊 Polymer
期
第317期
发表时间
20210918
关键词
Bio-based polyurethane;
Vitrimer-like;
Imine bond;
Rapidly-degradable;
Antibacterial property;
摘要
Synthesis of vitrimer with dynamic?covalent bond?is a surprising solution to overcome the inherent limitations of traditional?thermosets. A bio-based vitrimer-like?polyurethane?formed by?castor oil,?vanillin, m-xylylenediamine and 4,4′-dicyclohexylmethane?diisocyanate?in the preparation has superior mechanical properties, good?solvent resistance, good thermal stability. Furthermore, the existence of dynamic?imine?bond in the vitrimer-like polyurethane is prone for polyurethane to rapid stress relaxation behavior, remoldability, weldability, antibacterial ability. With the hydrolysis of the imine bond, the material can be rapidly degraded at 60?°C for 1?h. In addition, it's commendable that the material exhibits excellent reprocessability that can be maintained at 86% even after 3 consecutive smash/mold pressing cycles. This work provides a promising method to manufacture bio-based polyurethane thermosets with excellent reprocessability, rapidly-degradable and antibacterial property, which has also promoted the high-value utilization of biomass materials.
服务人员
尚玮姣
服务院士
宋湛谦
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